Implications of Heteroaggregation on Vertical Transport of Low-Density Polyethylene Particles in Quartz-Based Soil Column as Examined Using Laser-Direct Infrared (LDIR) Spectroscopy
Presenter: Marko Stephen Cerne
Faculty Sponsor: Baoshan Xing
School: UMass Amherst
Research Area: Environmental Science and Sustainability
Session: Poster Session 6, 4:15 PM - 5:00 PM, Auditorium, A59
ABSTRACT
While microplastics (MPs) are closely associated with ocean contamination, they are also ubiquitous in the soil. One source of terrestrial MPs is plastic mulching, a technique that covers agricultural soil with black sheets of low-density polyethylene (LDPE) to reduce soil erosion, weed growth, evaporation, and enhance plant productivity. Despite the benefits of plastic mulching, recent research suggests these MPs are detrimental to plant and soil health by reducing root nutrient uptake and lowering water retention. This study focuses on transport, observing the effects of soil hematite (Fe2O3) concentrations on the vertical movement of LDPE in soils.
The study will use multi-stage glass columns filled with simulated soil (Ssim), and LDPE initially mixed with the Ssim in the top stage. The main variable of this experiment is the concentration of hematite coating the quartz used as Ssim, which will vary between (0, 5, 10, 15, 22 mg/g quartz) columns. These columns are irrigated with simulated rainwater (Rsim) in wetting and drying cycles to simulate real-world watering conditions. After irrigation, the columns are deconstructed, LDPE is extracted, weighed, and imaged with an infrared microscope (LDIR) to determine the MPs concentration in each layer, revealing the depth of penetration.
This experiment is expected to show less LDPE vertical migration correlated with higher hematite concentrations in Ssim, due to surface charge interactions between LDPE and hematite. These results could be applied to different agricultural soils to determine the extent of MPs transport in soil associated with plastic mulching based on hematite content.